KHẢO SÁT ẢNH HƯỞNG CỦA HÀM LƯỢNG PHOTPHO ĐẾN TÍNH CHẤT LỚP PHỦ Ni-P VÀ ĐÁNH GIÁ KHẢ NĂNG CHỐNG ĂN MÒN CỦA LỚP PHỦ Ni-P ĐA LỚP ĐEN

Nguyễn Thị Yến1
1 Viện Độ bền nhiệt đới, Trung tâm Nhiệt đới Việt - Nga

Nội dung chính của bài viết

Tóm tắt

INVESTIGATE THE EFFECTS OF PHOSPHORUS CONTENT ON PROPERTIES OF Ni-P COATING AND EVALUATE THE CORROSION RESISTANCE OF BLACK MULTILAYER Ni-P COATING

The paper presents the effects of NaH2PO2 concentrations in electrodeposition solution on phosphorus contents and corrosion resistance of Ni-P layer. The results of SEM/EDX show that when the concentration of NaH2PO2 in solution increases, the content of phosphorus and corrosion resistance of the layer also increase and the alloy's state changes from coarse granules to a smooth surface. The paper also describes the electrodeposition method to make black Ni-P multilayer coating. The corrosion resistance of black multilayer Ni-P alloys including Ni-P (high phosphorus)/Ni-P (low phosphorus)/black Ni-P-Zn is 6 times higher than that of blackened steel when testing using salt spray methods.

Chi tiết bài viết

Tài liệu tham khảo

1. Changdong Gu, Jianshe Lian, Guangyu Li, Liyuan Niu, Zhonghao Jiang, High corrosion-resistant Ni-P/Ni/Ni-P multilayer coatings on steel, Surface & Coatings Technology, 2005, 197:61-67.
2. Fang Zhaoheng, Electrodeposition of amorphous Ni-P alloy coatings, Trans. Nonferrous Met. Soc. China, 1997, 7:148-151.
3. Fei Xing, Borui Zhao, Wenying Shi, Study on tunable fabrication of the ultra- black Ni-P film and its blacking mechanism, Electrochimica Acta, 2013, 100:157-163.
4. Hsien-Chung Huang, Sung-Ting Chung, Szu-Jung Pan, Wen-Ta Tsai, Chao- Sung Lin, Microstructure evolution and hardening mechanisms of Ni-P electrodeposits, Surface & Coatings Technology, 2010, 205:2097-2103.
5. Takadoum J., Black coating, The European Physical Journal Applied Physics, 2010, 3, p.52.
6. Nie S., Cai X. & Xiong S., Corrosion resistance of alternatively deposited layers of electroless Ni-P and electroplated Zn-Ni on cast steel substrate in neutral 5 wt-%NaCl solution, Corrosion Engineering, Science and Technology, 2006, 41:51-56.
7. Bachvarov V., Peshova M., Vitkova S., Boshkov N., Electrodeposition, structure and composition of ternary Zn-Ni-P alloys, Materials Chemistry and Physics, 2012, 136:999-1007.
8. ASTM B 571-97 (Reapproved 2003), Standard Practice for Qualitative Adhesion Testing of Metallic Coatings.
9. ASTM B117, Standard Practive of Operating Salt Spray (fog) Apparatus.
10. ASTM B 504-90, Standard Test Method for Measurement of Thickness of Metallic Coatings by the Coulometric Method.